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Yellowing of Polycarbonate

Because of the molecular structure of polycarbonate, the polymer is susceptible to yellowing through a variety of degradation mechanisms. Discoloration of polycarbonate can occur through oxidation, either during processing or as a result of elevated temperature exposure in air. Yellowing can also take place through sterilization, such as autoclaving, radiation, or ethylene oxide. Further, polycarbonate is highly susceptible to yellowing through ultraviolet radiation (UV) exposure.

When polycarbonate is exposed to ultraviolet radiation as sunlight, yellowing can take place rapidly. This discoloration is principally a surface phenomenon, approximately 25 micrometers deep, due to the penetration depth of the UV radiation into the polycarbonate.

Yellowing within polycarbonate occurs as a result of the formation of degradation breakdown products that absorb in the yellow range of the visible light spectrum. This includes substituted ortho-quinones, quinone methides, phenones and phenone derivatives, and bisphenol-A derivatives. Analytical techniques, including gas chromatography-mass spectroscopy (GC-MS) and Fourier transform infrared spectroscopy (FTIR), have been used to study the degradation mechanisms and characterize the breakdown products.

The discoloration of polycarbonate is accentuated by the high level of transparency, which results in a strong yellow hue.

The effects of UV exposure, as well as oxidation and hydrolytic degradation, can be assessed through accelerated aging followed by color evaluation and physical/mechanical testing. The image below shows the progressive yellowing of a polycarbonate resin, formulated without a UV stabilizer, through 1000 hours exposure in a QUV chamber.

The UV resistance of polycarbonate can be improved through compounding with additive UV stabilizers. As an alternative, the resistance can be developed as a protective coating.

Polycarbonate PC yellowing chemistry

Jeffrey A. Jansen

Jeffrey A. Jansen is the Engineering Manager and a Partner at The Madison Group. He was elected as a Fellow of the Society by the Society of Plastics Engineers. Jeff is a proven plastic professional with more than 30 years of experience solving problems and addressing opportunities related to polymeric materials. He specializes in failure analysis, material identification and selection, as well as compatibility, aging, and lifetime prediction studies for thermoplastic materials. Jeff has performed over 5,000 investigations, both for industrial clients and as a part of litigation. He regularly presents seminars and webinars, covering a wide range of topics related to plastics failure, material performance, testing, and polymer technology. Jeff is a graduate of Carroll College and the Milwaukee School of Engineering.